Modulation of cross polarization in motionally averaged solids by variable angle spinning NMR

作者：Espinosa Catalina A; Thureau Pierre; Shapiro Rebecca A; Litvak Ilya M; Martin Rachel W^*

来源：Chemical Physics Letters, 2011, 508(4-6): 314-319.

DOI：10.1016/j.cplett.2011.04.043

In systems where the dipolar couplings are partially averaged by molecular motion, cross-polarization is modulated by sample spinning. The cross-polariation efficiency in variable angle spinning (VAS) and Switched Angle Spinning (SAS) experiments on mobile samples is therefore strongly dependent on the spinning angle. We describe simulations and experimental measurements of these effects over a range of spinning angles from 0 degrees to 90 degrees.

• 出版日期2011-5-27