A new route for substitution of the bridging acetate on the oxo-centered triruthenium acetate cluster

作者:Yuge Hidetaka; Asahi Shin ichiro; Miyamoto T Ken*
来源:Dalton Transactions, 2009, (13): 2287-2289.
DOI:10.1039/b901050p

摘要

Deacetoxylation of the oxo-centered triruthenium acetate cluster by acetyl chloride or triethylsilyl chloride led to the formation of a versatile precursor [Ru(3)O(OAc)(5)(Cl)(4-methylpyridine)(2)(CNt-Bu)], whose chloro ligand was readily substituted by other bridging ligands, i.e. alkoxides, carboxylates or sulfides.

  • 出版日期2009