A photoluminescent 3D silver(I) polymer with mixed 2-naphthol-5-carboxylate and hexamethylenetetramine ligands, showing an unusual (3,4)-connected (6.7.8)(2)(4.6.7)(2)(4.7.8)(2)(7(2).8)(2)(6(2).7.8(3))(6(2).7(2).8.10) topology

作者：Fang Shao Ming^*; Ma Song Tao; Guo Liang Qi; Zhang Qiang; Hu Min; Zhou Li Ming; Gao Li Jun; Liu Chun Sen

来源：Inorganic Chemistry Communications, 2010, 13(1): 139-144.

DOI：10.1016/j.inoche.2009.10.029

• Silver(I) complex
• Naphthalene-based ligand
• Crystal structure
• Topology
• Luminescence

The reaction of AgClO(4) with 2-naphthol-5-carboxylic acid (HL) and hexamethylenetetramine (hmt) in the presence of 2,6-dimethylpyridine afforded a photoluminescent three-dimensional (3D) Ag(I) polymer {[Ag(6)(L)(mu(3)-hmt)(2)(mu(4)-hmt)(2)(ClO(4))](ClO(4))(4)(H(2)O)}(infin ity) (1), which exhibited an unusual (3,4)-connected (6.7.8)(2)(4.6.7)(2)(4.7.8)(2)(7(2).8)(2)(6(2).7.8(3))(6(2).7(2).8.10) topological network (L = 2-naphthol-5-carboxylate). Moreover, the luminescent properties of 1 have been briefly investigated.

• 出版日期2010-1
• 单位郑州轻工业大学