科研之友
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摘要
Molecular manganese fluorides were studied using quantum-chemical calculations at DFT and CCSD(T) levels and experimentally by matrix-isolation techniques. They were prepared by co-deposition of IR-laser ablated elemental manganese or manganese trifluoride with F-2 in an excess of Ne, Ar, or N-2 or with neat F-2 at 5-12 K. New IR bands in the Mn-F stretching region are detected and assigned to matrix-isolated molecular MnFx (x = 1-3).
- 出版日期2016
