A three-dimensional highly stable Zn(II) coordination polymer based on 1,4-benzeneditetrazolate (H2BDT): Synthesis, crystal structure, and luminescent properties

作者：Deng Ji Hua^*; Yuan Xiao Lin; Mei Guang Quan

来源：Inorganic Chemistry Communications, 2010, 13(12): 1585-1589.

DOI：10.1016/j.inoche.2010.09.023

• 1,4-benzeneditetrazolate
• Coordination polymer
• Zinc(II)
• Crystal structure
• Luminescence

1,4-benzeneditetrazolate [H2BDT] (1) and its 3D coordination polymer [Zn(BDT)](n) (2), have been synthesized and structurally characterized by infrared spectroscopy (IR), thermal gravimetric analysis (TG), and single-crystal/powder X-ray diffraction. The result of the single-crystal X-ray diffraction analysis indicates that 1 is a 3D supramolecular structure stabilized by intermolecular hydrogen bonds and pi ... pi stacking interactions. 2 is a 3D (4,4)-connected coordination polymer with the central metal Zn(II) ions linked together by BDT2- anions. Photoluminescent measurement for 2 in the solid state elucidates that 2 displays a strong photoluminescence at 469 nm, which suggests that 2 may be a potential blue-light material.

• 出版日期2010-12
• 单位宜春学院