Highly stable and selective Ru/NiFe2O4 catalysts for transfer hydrogenation of biomass-derived furfural to 2-methylfuran

作者：Wang, Baowei; Li, Chuang; He, Bo; Qi, Ji; Liang, Changhai^*

来源：Journal of Energy Chemistry, 2017, 26(4): 799-807.

DOI：10.1016/j.jechem.2017.04.008

• Ru/NiFe2O4
• Furfural
• 2-Methylfuran
• Transfer hydrogenation
• 2-Propanol

Spinel ferrites NiFe2O4 supported Ru catalysts have been prepared via a simple sol-gel route and applied for converting biomass-derived furfural to 2-methylfuran. The as-prepared catalysts were characterized by thermogravimetric analysis (TG), N-2 adsorption-desorption, X-ray diffraction (XRD), scanning electronic microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Results showed that the catalysts had well-dispersed Ru active sites and large surface area for calcination temperature ranging from 300 to 500 degrees C. The conversion of biomass-derived furfural into 2-methylfuran was conducted over Ru/NiFe2O4 through catalytic transfer hydrogenation in liquid-phase with 2-propanol as the hydrogen source. A significantly enhanced activity and increased 2-methylfuran yield have been achieved in this study. Under mild conditions (180 degrees C and 2.1 MPa N-2), the conversion of furfural exceeds 97% and 2-methylfuran yield was up to 83% over the catalyst containing 8 wt% Ru. After five repeated uses, the catalytic activity and the corresponding product yield remained almost unchanged. The excellent catalytic activity and recycling performance provide a broad prospects for various practical applications.

• 出版日期2017-7
• 单位大连理工大学