Diastereoselective Reduction of beta-(1,3-Dioxan-4-yl)ketones

作者：Matsumoto Akira; Asano Keisuke^*; Matsubara Seijiro

来源：Synlett, 2015, 26(13): 1872-1874.

DOI：10.1055/s-0034-1378725

• diastereoselective reduction
• chiral acetal
• 1,3-dioxane
• 1,3-polyol
• polyketide

Stereoselective reduction of beta-(1,3-dioxan-4-yl) ketones is an important step in the efficient synthesis of chiral 1,3-polyols, a typical structure of polyketides. In this study, we carried out investigations to optimize the conditions for diastereoselective reduction.

• 出版日期2015-8