Direct access to pyrazolo(benzo)thienoquinolines. Highly effective palladium catalysts for the intramolecular C-H heteroarylation of arenes

作者:Churruca Fatima; Hernandez Susana; Perea Maria; SanMartin Raul*; Dominguez Esther
来源:Chemical Communications, 2013, 49(14): 1413-1415.
DOI:10.1039/c2cc37905h

摘要

A short and atom-efficient strategy to obtain a series of pyrazolo(benzo)thienoquinolines is developed. Alternative catalytic systems for the key intramolecular direct heteroarylation of arenes are presented and include the first example of C-H (hetero)arylation of (hetero)arenes catalyzed by very low catalyst loadings of a palladium source.

  • 出版日期2013