Aminoborylation/Suzuki-Miyaura tandem cross coupling of aryl iodides as efficient and selective synthesis of unsymmetrical biaryls

作者：Marciasini Ludovic; Richy Nicolas; Vaultier Michel; Pucheault Mathieu^*

来源：Chemical Communications, 2012, 48(10): 1553-1555.

DOI：10.1039/c1cc14605j

Sequential borylation of a first aryl iodide using a dialkyl-aminoborane followed by a Suzuki-Miyaura cross coupling of second aryl iodide ended up with an efficient, selective and practical synthesis of unsymmetrical biaryls. This tandem coupling shows a wide range of applicability.

• 出版日期2012