科研之友
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摘要
Isothermal rheological behaviors of waterborne polyurethane (WPU)/starch aqueous dispersions during cure were investigated with a small-amplitude oscillatory shear flow experiment to evaluate their crosslinked structure and to predict their mechanical properties, for the first time. An abrupt increase in the elastic storage modulus (G'), the viscous loss modulus (G ''), the complex dynamic viscosity (eta*) and the loss tangent (tan delta) was observed during the curing process of the dispersions, as a result of the formation of a fractal polymer gel. The gel point (t(gel)) was determined from the intersection in tan delta vs curing time for different constant shear frequencies, where tan delta was frequency independent and all curves crossed over, indicating the validity of the Winter-Chambon criterion for the complex system. The values of the power law exponent (n) and the gel strength (S(g)) at the gel point indicated that with an increase of starch content the crosslinked WPU/starch gels underwent a transition from weak fractal to strong elastic ones. Moreover, the WPU/starch composite sheets, obtained from the aqueous dispersions with relatively high S(g) values, also exhibited the increased tensile strength (sigma(b)) and Young's modulus (E). Their structure-mechanical properties relationship and the phase transitions of dispersed starch-dual-phase continuity-starch matrix were revealed. This work confirmed that the rheological characters could be used to predict the mechanical properties of the WPU materials blended with natural polymer.
- 出版日期2009-11-3
- 单位武汉大学
