2,6-bis-methylsulfanyl-[1,3,5]thiadiazine-4-thione as a Ag+-seleetive ionophore

作者：Mahajan RK^*; Sood P; Mahajan MP; Singh P

来源：Analytical Sciences, 2004, 20(10): 1423-1426.

DOI：10.2116/analsci.20.1423

A silver ion-selective electrode was prepared with a polymeric membrane incorporating 2,6-bis-methylsulfanyl[1,3,5]thiadiazine-4-thione as an ionophore, tri-n-butylphosphate (TBP) as a plasticizer and sodium tetraphenylborate (NaTPB) as an additive. The electrode exhibited a near-Nernstian response of 52 mV/decade over a wide linear concentration range of 1.0 x 10(-5) - 1.0 x 10(-1) M with a lower detection limit of 9.77 x 10(4) M. The electrode exhibited excellent selectivity for silver ion over many of the alkali, alkaline-earth and transition metal ions. The electrode worked well over a wide pH range of 1.77 - 7.13. The response time of the electrode was less than 20 s. The sensor can be applied as indicator electrode for the potentiometric titration of Ag+ ions with Cl- ions.

• 出版日期2004-10