Absorption of Dilute Sulfur Dioxide in Aqueous Poly-Ethylene Glycol 200 Solutions at 298.15 K and 122.60 kPa

作者：Zhang, Jianbin^*; Zheng, Yan; Wu, Shijun; Hu, Yuqiang; Yan, Ligang

来源：Asian Journal of Chemistry, 2012, 24(10): 4729-4732.

• Absorption
• Flue gas desulfurization
• Phase equilibrium
• Sulfur dioxide

In present work, isothermal gas-liquid equilibrium (GLE) data are measured for the absorption of dilute SO2 in various aqueous polyethylene glycol 200 (PEG) solutions at 298.15 K and 122.60 kPa and SO2 partial pressures in the range of (0.8-127) Pa. Measurements were carried out by a saturation method using a glass absorption apparatus, which were controlled at constant temperature using a thermostatic circulation bath with a Beckmann thermometer. The gas-liquid equilibrium data were measured with relative uncertainties within +/- 0.02 K for temperature, +/- 0.133 kPa for total pressures, +/- 0.6 % for SO2 concentration in the liquid phase and +/- 3.5 % for SO2 volume fraction in the gas phase. The measurement showed that the solubility of SO2 in the system PEG (1) + water (2) increased with increasing PEG concentration in the mass fraction range of w(1) = (0.60-1.00) and the solubility of SO2 in the PEG (1) + water (2) system presented a minimum at the mass fraction of w(1) = 0.60 of 101 mg dm(-3) when SO2 in the gas phase is designed at Phi(SO2) = 5 x 10(-4). The peculiarity of this work is used to provide important gas-liquid equilibrium data for the design and operation of the absorption and desorption processes in flue gas desulfurization with potential industrial application of various aqueous solutions of poly-ethylene glycol 200.

• 出版日期2012-10
• 单位内蒙古工业大学; 呼和浩特职业学院