An N-heterocyclic carbene phenanthroline ligand: synthesis, multi-metal coordination and spectroscopic studies

作者:Webster Alyssa A; Prasad Shyamal K K; Hodgkiss Justin M*; Hoberg John O
来源:Dalton Transactions, 2015, 44(8): 3728-3736.
DOI:10.1039/c4dt03086a

摘要

Dimetal complexes of a new N-heterocyclic carbene/phenanthroline ligand have been synthesized. Coordination of both ruthenium and rhenium to the phenanthroline moiety in combination with platinum at the carbene moiety are reported. Steady-state and time-resolved optical absorption and photoluminescence spectra were obtained for the complexes. These results illustrate significant changes occur with the incorporation of the second metal, and that the specific metal

  • 出版日期2015