Melamine Modification of Spherical Activated Carbon and Its Effects on Acetylene Hydrochlorination

作者：Han Weijie; Wang Xugen; Zhu Mingyuan; Zhang Haiyang; Chen Kun; Wang Qinqin; Li Xiaoyan; Dai Bin^*

来源：Journal of Wuhan University of Technology-Materials Science Edition, 2014, 29(6): 1147-1151.

DOI：10.1007/s11595-014-1057-6

• spherical activated carbon
• melamine modification
• catalytic properties
• acetylene hydrochlorination

Commercial spherical activated carbon (SAC) was modified by impregnation to enhance the catalytic properties of SAC in acetylene hydrochlorination through melamine modification. Different modification conditions for SAC with nitrogen were compared by changing the SAC-Melamine ratios. The effect of carbonization temperature on the modifi cation was also investigated. Surface chemistry and adsorption properties of the modifi ed and unmodifi ed SACs were studied by scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), elementary analysis, BET, and temperature-programmed desorption (TPD). Moreover, the catalytic properties of SAC in acetylene hydrochlorination under differently modifi ed conditions were also investigated. Elemental analysis showed that the nitrogen content of the modifi ed SAC was greatly improved. XPS revealed that nitrogen mainly exists in Pyrrole nitrogen and Pyridine nitrogen. TPD showed that desorption of C2H2 was changed by modifi cation. The conversion rate of acetylene was up to 70% under the following reaction conditions: temperature, 150.; C2H2 hourly space velocity (GHSV), 36 h(-1); feed volume ratio V (HCl)/V (C2H2) = 1.15. The catalytic properties of SAC were improved significantly via melamine modifi cation.

• 出版日期2014-12
• 单位石河子大学