A hierarchical homogeneous core-shell structure of TiO2 hollow microspheres for high efficiency dye-sensitized solar cells

作者：Yu, Yuan-Yuan; Lei, Bing-Xin^*; Xie, Min-Li; Huang, Guo-Lei; Sun, Wei; Sun, Zhen-Fan

来源：Advanced Powder Technology, 2015, 26(4): 1072-1078.

DOI：10.1016/j.apt.2015.04.017

• Microsphere
• Core-shell structure
• Titania
• Light-scattering
• Dye-sensitized solar cell

Core-shell TiO2 (cs-TiO2) hollow microspheres are prepared via a facile hydrothermal method, by using titanium potassium oxalate precursor in dilute sulfuric acid. The characterization shows that the as-prepared TiO2 microspheres have core-shell structure. The diameters of cs-TiO2 microspheres are in the range of 2-5 mu m. The optical investigation evidences that the cs-TiO2 microsphere film exhibits a prominent light-scattering effect at a wavelength range of 600-800 nm. The cs-TiO2 microspheres are applied as a scattering layer on top of a nanocrystalline P25 film, serving as the photoanode of dye-sensitized solar cells (DSSCs). A high efficiency of 7.7% is achieved after introducing the cs-TiO2 hollow microsphere scattering layer, compared with 6.21% for the photoanode with commercial P25. Based on the optical investigation and electrochemical impedance measurement, the improved efficiency can be ascribed to the enhanced light-scattering ability and the reduced interface recombination rate.

• 出版日期2015-7
• 单位海南师范大学