A facile method to fabricate Cu-0 supported on nanofibers as efficient catalyst using N-arylation reactions

作者：Li, Hengyu; Bai, Jie^*; Wang, Junzhong; Li, Chunping

来源：Molecular Catalysis, 2017, 431: 49-56.

DOI：10.1016/j.mcat.2017.01.005

• Cu-based catalyst
• Nanofibers
• Catalyst
• N-arylation reaction

Glucose was dispersed in polyacrylonitrile (PAN) nanofibers to develop a novel supporter for reducing and anchoring Cu-0 by hydrothermal process. The newly developed catalyst was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), and amorphous Cu-0 were obtained. The prepared Cu-0 nanocatalyst was investigated as a heterogeneous catalyst for N-arylation reaction of N-heterocyclic compounds and a wide range of aryl iodides including iodobenzene, electron-rich and electron-poor aryl iodides, which performed excellent catalytic activity.

• 出版日期2017-4
• 单位内蒙古工业大学