Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(V)-oxo complex

作者：Kwon Eunji; Cho Kyung Bin; Hong Seungwoo; Nam Wonwoo^*

来源：Chemical communications, 2014, 50(42): 5572-5575.

DOI：10.1039/c4cc01058b

Hydroxylation of alkanes by a mononuclear nonheme iron(V)-oxo complex, [Fe(V)(O)(TAML)](-), is initiated by a rate-determining hydrogen atom(H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction-oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.

• 出版日期2014