A 3D chiral Co(II) coordination polymer featuring unique self-interpenetrating topology

作者：Wang Xiao Fang^*; Liu Yang

来源：Inorganic Chemistry Communications, 2013, 27: 76-78.

DOI：10.1016/j.inoche.2012.10.005

• Coordination polymer
• Chirality
• Hydrothermal synthesis
• Crystal structure
• Magnetism

A 3D chiral coordination polymer, [Co-3(hfipbb)(2)(D-Hcam)(2)(hPP)(2)(H2O)(2)]center dot 2H(2)O (1) (H(2)hfipbb = 2,2-bis(4-carboxyphenyl)hexafluoropropane, D-H(2)cam=D-(+)camphoric acid, bpp=1,3-di(4-pyridyl)propane), has been hydrothermally synthesized, which features an interesting 6-connected self-interpenetrating (4(4).6(10).8) topological network. There exists predominantly antiferromagnetic interaction between the Co(II) centers in 1.

• 出版日期2013-1
• 单位辽宁大学