Multifunctional Supramolecular Hybrid Materials Constructed from Hierarchical Self-Ordering of In Situ Generated Metal-Organic Framework (MOF) Nanoparticles

作者：Chaudhari Abhijeet K; Han Intaek; Tan Jin Chong

来源：Advanced Materials, 2015, 27(30): 4438-4446.

DOI：10.1002/adma.201501448

• hierarchical self-assembly
• metal-organic frameworks
• sol-gel
• stimuli-responsive materials
• supramolecular materials

A synergistic approach is described to engineer supramolecular hybrid materials based on metal-organic frameworks, encompassing HKUST-1 nanoparticles formed in situ, coexisting with an electrically conducting gel fiber network. The following findings are made: i) multistimuli-responsive structural transformation via reversible sol-gel switching and ii) radical conversion of a soft hybrid gel into a mechanically malleable, viscoelastic matter.

• 出版日期2015-8-12