Diaquadiperchlorato[mu-11,23-dimethyl-3,7,15,19-tetraazatricyclo[19.3.1. 1(9,13)]hexacosa-1(25),2,7,9,-11,13(26),14,19,21,23-decaene-25,26-diolat o-1 kappa N-2,N ';2 kappa N-2 '',N ''';1 : 2 kappa O-2 : O ']dicadmium(II) diaqua[mu-11,23-dimethyl-3,7,15,19-tetraazatricyclo[19.3.1.1(9,13)]hexac osa-1(25), 2,7,9,11,13(26),-14,19,21,23-decaene-25,26-diolato-1 kappa N-2, N ';2 kappa N-2 '', N ''';1 : 2 kappa O-2 : O ']dicadmium(II) diperchlorate

作者：Liu B; Zhou H; Pan ZQ^*; Hu XL; Chen L

来源：Acta Crystallographica Section E-Structure Reports Online, 2005, 61: M1295-M1297.

DOI：10.1107/S1600536805017599

In the title complex, [Cd-2(C24H26N4O2)(ClO4)(2)(H2O)(2)][Cd-2(C24H26N4O2)(H2O)(2)](ClO4)(2), the two distinct macro-cycles adopt essentially flat structures. They each encapsulate two Cd atoms. One Cd coordination polyhedron, completed by a water O atom and a perchlorate O atom, is distorted octahedral, while the other is best described as a CdN2O3 square-based pyramid, with water in the apical site. Both dinuclear complexes are centrosymmetric.

• 出版日期2005-7
• 单位武汉工程大学; 武汉大学