Determination of ultratrace amounts of plutonium in high saline groundwater by inductively coupled plasma mass spectrometry

作者：Tian M^*; Han X Y; Zhai X F; Wang Y; Zhang R R

来源：Journal of Radioanalytical and Nuclear Chemistry, 2013, 298(1): 111-117.

DOI：10.1007/s10967-013-2459-1

• High saline groundwater
• Plutonium
• Sequential co-precipitation
• Dowex1 x 4 resin
• ICP-MS

For determination of ultratrace amounts of plutonium in high saline groundwater, large-volume sampling and preconcentration are necessary. However, traditional co-precipitation methods, such as Fe(OH)(3), Ca(OH)(2)-Mg(OH)(2) and hydroxide-carbonate co-precipitation, are unable to meet the requirements of preconcentration of the ultratrace plutonium in high saline groundwater. In this paper, the ultratrace plutonium in high saline groundwater was concentrated by sequential co-precipitation with MnO2 and Fe(OH)(3), and purified by two-stage anion-exchange separation on Dowex1 x 4 resin column. Quadrupole ICP-MS was employed for the determination of Pu-239 with Pu-242 spiked. After co-precipitation and purification, the major matrix elements were significantly decreased to mu g mL(-1) level and decontamination factor of uranium is better than 10(6). The detection limit for Pu-239 in 50 L high saline water is 2.1 x 10(-16) g L-1. Three high saline fountain samples (total dissolved solids more than 20 g L-1) from Dunhuang region of China were analyzed using this method. The concentrations of Pu-239 in these samples were 0.48 +/- A 0.2 x 10(-15), 1.40 +/- A 0.10 x 10(-15) and 2.13 +/- A 0.21 x 10(-15) g L-1 respectively. The recovery obtained for 7 pg of Pu-242 spiked into real high saline-water samples was all above 70 %.

• 出版日期2013-10
• 单位西北核技术研究所