科研之友
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摘要
A variety of terminal alkynes were converted into the corresponding 4-(2-oxoallcoxy)butyl methanesulfonates via a gold-catalyzed intermolecular oxidation reaction using 8-ethyl-quinoline N-oxide as the oxidant and THF as the solvent. This reaction is proposed to proceed through the ring-opening of THF via an alpha-oxo gold carbene intermediate.
- 出版日期2014-6-5
- 单位湖南大学
