Understanding anomalous current-voltage characteristics in microchannel-nanochannel interconnect devices

作者：Nandigana Vishal V R; Aluru N R^*

来源：Journal of Colloid and Interface Science, 2012, 384: 162-171.

DOI：10.1016/j.jcis.2012.06.004

• Micro-nanochannel
• Concentration polarization
• Space charge redistribution
• Overlimiting current
• AC/DC field
• Current rectification

The integration of a microchannel with a nanochannel is known to exhibit anomalous nonlinear current-voltage characteristics. In this paper, we perform detailed numerical simulations considering a 2-D nonlinear ion transport model, to capture and explain the underlying physics behind the limiting resistance and the overlimiting current regions, observed predominantly in a highly ion-selective nanochannel. We attribute the overlimiting current characteristics to the redistribution of the space charges resulting in an anomalous enhancement in the ionic concentration of the electrolyte in the induced space charge region, beyond a critical voltage. The overlimiting current with constant conductivity is predicted even without considering the effects of fluidic nonlinearities. We extend our study and report anomalous rectification effects, resulting in an enhancement of current in the non-ohmic region, under the application of combined AC and DC electric fields. The necessary criteria to observe these enhancements and some useful scaling relations are discussed.

• 出版日期2012-10-15