Nanosized TiN-SBR hybrid coating of stainless steel as bipolar plates for polymer electrolyte membrane fuel cells

作者：Kumagai Masanobu; Myung Seung Taek^*; Asaishi Ryo; Sun Yang Kook; Yashiro Hitoshi

来源：Electrochimica Acta, 2008, 54(2): 574-581.

DOI：10.1016/j.electacta.2008.07.043

• TiN
• SBR
• Electrophoretic deposition
• Bipolar plates
• Fuel cell

In attempt to improve interfacial electrical conductivity of stainless steel for bipolar plates of polymer electrolyte membrane fuel cells, TiN nanoparticles were electrophoretically deposited on the surface of stainless steel with elastic styrene butadiene rubber (SBR) particles. From transmission electron microscopic observation, it was found that the TiN nanoparticles (ca. 50 nm) surrounded the spherical SBR particles (ca. 300-600 nm), forming agglomerates. They were well adhered on the surface of the type 310S stainless steel. With help of elasticity of SBR, the agglomerates were well fitted into the interfacial gap between gas diffusion layer (GDL) and stainless steel bipolar plate, and the interfacial contact resistance (ICR), simultaneously, was successfully reduced. A single cell using the TiN nanoparticles-coated bipolar plates, consequently, showed comparable cell performance with the graphite employing cell at a current density of 0.5 A cm(-2) (12.5 A). Inexpensive TiN nanoparticle-coated type 310S stainless steel bipolar plates would become a possible alternate for the expensive graphite bipolar plates as use in fuel cell applications.

• 出版日期2008-12-30