A 2D coordination polymer with brick-wall network topology based on the [Cu(NCS)(2)(pn)] monomer

作者：Legendre A O; Mauro A E^*; Ferreira J G; Ananias S R; Santos R H A; Netto Adelino V G

来源：Inorganic Chemistry Communications, 2007, 10(7): 815-820.

DOI：10.1016/j.inoche.2007.04.005

• supramolecular chemistry
• self-assembly
• copper(II)
• coordination polymer
• hydrogen bonding

The new complex [Cu(NCS)(2)(pn)] (1) (pn = 1,3-propanediamine) has been synthesized and characterized by elemental analysis, infrared and electronic spectroscopy. Single crystal X-ray diffraction studies revealed that complex 1 is made up of neutral [Cu(NCS)(2)(pn)] units which are connected by mu-1,3,3-thiocyanato groups to yield a 2D metal-organic framework with a brick-wall network topology. Intermolecular hydrogen bonds of the type NH...SCN and NH...NCS are also responsible for the stabilization of the crystal structure.

• 出版日期2007-7