科研之友
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摘要
<jats:title>Abstract</jats:title><jats:p>Synthesis of a water soluble ruthenium complex bearing PNP‐pincer ligand has been described. The complex in presence of KOBu<jats:sup><jats:italic>t</jats:italic></jats:sup> was found to be efficient catalyst for the acceptorless alcohol dehydrogenation (AAD) in aqueous medium. This selective synthetic protocol transforms secondary alcohols to ketones and primary alcohols to aldehydes without formation of any unwanted side products and produces only hydrogen as the sole by‐product.</jats:p>
- 出版日期2018-4-9
