摘要

Raman active phonon in orthorhombic perovskite La0.7Sr0.3MnO films and ZnO/LSMO multi-films were focused by measuring Raman spectra of 325 nm and 512nm laser in scattering configurations. The results show that the spin-orbit is caused by anomalies tilt of MnO6 octahedron. The transfer of d(x)(2)-(2)(y) orbits dynamics is in the background of the ferro-orbital order state of crystal stabilized d(3z)(2)-r(2) orbit effect. The kinetic energy gain achieved by the orbital competition, strong crystal field and charge order of energy band splitting. The LSMO/ZnO junction exhibits excellent junction behavior over the temperature range of 77-300 K.