A cobalt polypyrrole composite catalyzed cathode for the direct borohydride fuel cell

作者：Qin H Y; Liu Z X; Yin W X; Zhu J K; Li Z P^*

来源：Journal of Power Sources, 2008, 185(2): 909-912.

DOI：10.1016/j.jpowsour.2008.08.047

• Direct borohydride fuel cell
• Cathode
• Non-precious metal
• Cobalt polypyrrole carbon
• Cell performance

A cobalt polypyrrole carbon (Co-PPY-C) composite has been attempted for use as a cathode catalyst in a direct borohydride fuel cell (DBFC). A Co-PPY-C composite has been fabricated in laboratory and characterized by the field emission scanning electron microscopy, transmission electron microscopy, as well as X-ray photoemission spectroscopy. Fabricated Co-PPY-C catalyst demonstrates good short-term durability and activity which are comparable to those obtained from the Pt/C catalyst. A maximum power density of 65 mW cm(-2) has been achieved at ambient conditions. This research concludes that metallo-organic coordination compounds would be potential candidates for use as cathode catalysts in the DBFC.

• 出版日期2008-12-1
• 单位浙江大学