H3PW12O40-[bmim][FeCl4]: A novel and green catalyst-medium system for microwave-promoted selective interconversion of alkoxymethyl ethers into their corresponding nitriles, bromides and iodides

作者：Mohammadpoor Baltork Iraj^*; Moghadam Majid; Tangestaninejad Shahram; Mirkhani Valiolah; Mirjafari Arsalan

来源：Comptes Rendus Chimie, 2010, 13(12): 1468-1473.

DOI：10.1016/j.crci.2010.03.015

• Methoxymethyl ether
• Interconversion
• Microwave irradiation
• H3PW12O40@[bmim][FeCl4]

In the present work, the catalytic activity of 12-tungstophosphoric acid immobilized on [bmim][FeCl4]] ionic liquid as a highly efficient and eco-friendly catalytic system for rapid and chemoselective direct conversion of MOM- or EOM-ethers into their corresponding nitrites, bromides and iodides under microwave irradiation is reported. In these reactions, the products are obtained in high yields. The catalyst exhibited remarkable reactivity and was reused several times.

• 出版日期2010-12