A Facile Approach to Fabrication of Novel Magnetic Hydrogels Crosslinked by Multi-Functional Pomegranate-Like Nanospheres

作者:Xia, Mengge; Wang, Yiheng; Zhang, Yan; Cheng, Yanhua; Chen, Shaohua; Wang, Ruili; Meng, Zhouqi; Zhu, Meifang*
来源:Australian Journal of Chemistry, 2014, 67(1): 112-120.
DOI:10.1071/CH13365

摘要

A facile approach was explored to fabricate a novel magnetic hydrogel using pomegranate-like functional magnetic nanospheres (FMNs) as photoactive crosslinker and polyacrylamide as polymer matrix by photoinitiated free radical polymerization. These novel pomegranate-like FMNs were prepared by embedding Fe3O4 nanoparticles into polystyrene by miniemulsion polymerization. The effect of FMN concentration, acrylamide monomer molar concentration, polymerization time on the magnetic properties, morphology, swelling behaviour, and dynamic mechanical properties of magnetic hydrogels were systematically investigated. Our synthetic route expands the application of these materials in the fields of smart magnetic switches, targeted drug release, biomimetic sensors, and chemical devices.