Aquadipyridinebis(N-p-tolysulfonyl-L-leucinato)nickel(II)

作者:Tai Xi Shi*
来源:Acta Crystallographica Section E-Structure Reports Online, 2010, 66: M1346-U128.
DOI:10.1107/S1600536810038493

摘要

In each of the two molecules in the asymmetric unit of the title compound, [Ni(C13H18NO4S)(2)(C5H5N)(2)(H2O)], the geometry of the Ni2+ ion is an extremely distorted trans-NiN2O4 octahedron, arising from its coordination by one water molecule, two pyridine molecules, and one O-monodentate and one O, O'-bidentate deprotonated N-p-tolysulfonyl-L-leucine ligand. In the crystal, molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds, forming chains along the c axis. An intramolecular O-H center dot center dot center dot O hydrogen bond occurs in one of the molecules.

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