A Biomimetic Approach to Enhancing Interfacial Interactions: Polydopamine-Coated Clay as Reinforcement for Epoxy Resin

作者：Yang Liping; Phua Si Lei; Teo Jun Kai Herman; Toh Cher Ling; Lau Soo Khim; Ma Jan; Lu Xuehong^*

来源：ACS Applied Materials & Interfaces, 2011, 3(8): 3026-3032.

DOI：10.1021/am200532j

• biomimetics
• dopamine
• clay
• nanocomposite
• interface

A facile biomimetic method was developed to enhance the interfacial interaction in polymer-layered silicate nanocomposites. By mimicking mussel adhesive proteins, a monolayer of polydopamine was constructed on clay surface by a controllable coating method. The modified clay (D-clay) was incorporated into an epoxy resin, it is found that the strong interfacial interactions brought by the polydopamine benefits not only the dispersion of the D-clay in the epoxy but also the effective interfacial stress transfer, leading to greatly improved thermomechanical properties at very low inorganic loadings. Rheological and infrared spectroscopic studies show that the interfacial interactions between the D-clay and epoxy are dominated by the hydrogen bonds between the catechol-enriched polydopamine and the epoxy.

• 出版日期2011-8
• 单位南阳理工学院