Aqua(1,10-phenanthroline-kappa N-2,N ')bis(trimethylacetato)-kappa O-2,O ';kappa O-cobalt(II)

作者:Chen Xiao Dan; Chen Hong Xian; Li Zhong Shu; Zhang Huai Hong; Sun Bai Wang*
来源:Acta Crystallographica Section E-Structure Reports Online, 2009, 65(8): M997-U1598.
DOI:10.1107/S1600536809027251

摘要

In the title compound, [Co(C5H9O2)(2)(C12H8N2)(H2O)], the Co-II atom is coordinated in a distorted octahedral environment by three carboxyl O atoms of two trimethylacetate ligands, one aqua O atom and two N atoms from 1,10-phenanthroline. The crystal structure is stabilized by O-H center dot center dot center dot O hydrogen bonds and pi-pi stacking interactions [interplanar distance between interdigitating 1,10-phenanthroline ligands = 3.523 (2) angstrom]