A N-heterocyclic tetracarbene Pd(II) moiety containing a Pd(II)-Pb(II) bimetallic MOF for three-component cyclotrimerization via benzyne

作者：Dong, Ying; Li, Yue; Wei, Yong-Liang; Wang, Jian-Cheng; Ma, Jian-Ping; Ji, Jun; Yao, Bing-Jian; Dong, Yu-Bin^*

来源：Chemical communications, 2016, 52(69): 10505-10508.

DOI：10.1039/c6cc04570g

• COUPLING REACTIONS
• EFFICIENT ROUTE
• COMPLEXES
• CATALYSIS
• ARYNES
• COCYCLOTRIMERIZATION
• TRIPHENYLENES
• CHEMISTRY
• CARBENES
• WATER

A novel Pd(II)-Pb(II) bimetallic metal-organic framework Pd(II)-Pb(II)-MOF (B) which contains an N-heterocyclic tetracarbene Pd(II) moiety was synthesized based on a chelating N-heterocyclic dicarbene Pd(II)-NHDC ligand (A) under solvothermal conditions. It can be a highly active heterogeneous catalyst for three-component cyclotrimerization via benzyne species.

• 出版日期2016
• 单位山东师范大学