A Cu(II)-based strategy for catalytic enantioselective beta-borylation of alpha,beta-unsaturated acceptors

作者：Zhu Lei; Kitanosono Taku; Xu Pengyu; Kobayashi Shu^*

来源：Chemical Communications, 2015, 51(58): 11685-11688.

DOI：10.1039/c5cc04295j

Cu(I)-based chemistry has flourished over the last decade because of the reliable use of species such as soft acids. However, the unique nature of Cu(II) catalysts allows the well-documented Cu(I)-based chemistry to be extended. Prominent advantages of this approach include the ease of handling, the avoidance of strong base, and a wider substrate scope in enantioselective beta-borylation.

• 出版日期2015