6-(1-Methylethyl)-12-phenyl-5,6,7,12-tetrahydrodibenz[c,f][1,5]azasiloci ne

作者:Goto Kei*; Fukushima Akihiro; Kawashima Takayuki
来源:Acta Crystallographica Section E-Structure Reports Online, 2010, 66(1): O20-U1267.
DOI:10.1107/S1600536809050909

摘要

The title compound, C(23)H(25)NSi, has an eight-membered silicon-containing heterocyclic ring with an intramolecular N center dot center dot center dot Si close contact, the transannular distance of which is 2.6294 (18) angstrom. The resulting geometry about the Si atom is distorted trigonal-bypyramidal, with the N and H atoms occupying apical sites. The dihedral angle between the aromatic rings fused to the eight-membered ring is 63.27 (7)degrees.

  • 出版日期2010-1

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