Nickel(0)-Catalyzed Equilibrium Reaction of 3-Pentenenitrile

作者：Dong Jianxun^*; Shi Yukun; Hu Xiaojing; Feng Xiaoyan; Song Juanjuan; Ding Zhenzhen; Liu Xiangming; Huang Weiping

来源：Chinese Journal of Organic Chemistry, 2012, 32(3): 627-631.

DOI：10.6023/cjoc1107202

• zero-valent nickel
• 3-pentenenitrile
• 2-methylglutaronitrile
• adiponitrile
• reaction equilibrium

The equilibrium reaction of 3-pentenenitrile was carried out in the system containing Ni(0), P-ligand and anhydrous ZnCl2. The equilibrium state of 3-pentenenitrile was affected by factors such as reaction temperatures and different ligands, which were investigated. The FTIR-ATR was used to monitor the reaction process of 3-pentenenitrile turning into 2-methylglutaronitrile and adiponitrile in absence of HCN and the possible reaction mechanism was proposed.

• 出版日期2012-3
• 单位南开大学