A unique zinc-organic framework constructed through in situ ligand synthesis for conversion of CO2 under mild conditions and as a luminescence sensor for Cr2O72-/CrO42-

作者：Song, Tian-Qun; Dong, Jie; Gao, Hong-Ling; Cui, Jian-Zhong^*; Zhao, Bin^*

来源：Dalton Transactions, 2017, 46(40): 13862-13868.

DOI：10.1039/c7dt02819a

• CARBON-DIOXIDE
• COORDINATION POLYMERS
• TETRAZOLE FORMATION
• CYCLIC CARBONATES
• CYCLOADDITION
• OXIDE
• ADSORPTION
• CATALYSTS
• NITRILES
• EPOXIDES

A novel zinc-organic framework, {[Zn-3(tza)(2)(mu(2)-OH)(2)(H2O)(2)]center dot H2O}(n) (1) (H(2)tza = 1H-tetrazolate-5-acetic acid), was synthesized through an in situ generated tetrazole ligand under hydrothermal conditions. In compound 1, tza(2-) ligands and Zn2+ are interlinked to form 2D layers, which are further pillared through mu(2)-OH groups to generate a 3D framework. Thermogravimetric analysis and powder X-ray diffraction confirm that 1 has high thermal stability, pH stability and solvent stability. Catalytic studies show that 1 exhibits excellent catalytic ability for the cycloaddition of CO2 with epoxides under 50 degrees C and 0.1 MPa. Importantly, 1 can be reused at least six times. Furthermore, luminescence investigations indicate that 1 can serve as a recyclable luminescence sensor to efficiently detect Cr2O72-/CrO42-, and the detection limit can reach 10 (6) mol L (1) and 4 x 10 (-)6 mol L (1), respectively.

• 出版日期2017-10-28
• 单位南开大学; 天津大学