摘要

A chiral 3-D inorganic-organic hybrid coordination polymer, {[Cu6I5(L)(3)](BF4)center dot H2O}(n) [L = 1,4-bis(2-pyrimidinesulfanylmethyl) benzene], containing a 2-D inorganic [(Cu6I5)(+)](n) layer composed of three interwoven 1D [CuI](n) helices in different directions and connected by ligand L through nitrogen and sulfur atoms, was synthesized and characterized.