Direct synthesis of Ti-containing SBA-16-type mesoporous material by the evaporation-induced self-assembly method and its catalytic performance for oxidative desulfurization

作者：Shah Asma Tufail; Li Baoshan^*; Abdalla Zaki Eldin Ali

来源：Journal of Colloid and Interface Science, 2009, 336(2): 707-711.

DOI：10.1016/j.jcis.2009.04.026

• Mesoporous materials
• Titanium
• Evaporation-induced self-assembly method
• F127
• Oxidative desulfurization
• Nitrogen adsorption

A novel Ti-containing SBA-16-type mesoporous material (with various Ti loadings of 5, 10, and 15 wt%) was synthesized by an evaporation-induced self-assembly method using F127 copolymer as template. The materials were characterized by XRD, FTIR, TG-DTA, N(2) adsorption, SEM, HRTEM, and XPS. The characterization results show that the material possesses high thermal stability, thick pore walls (10.43-10.68 nm), and high Surface area (642.26-691.5 m(2)/g) with a mesoporous worm-like structure, and titanium was successfully incorporated into the silica matrix with a tetrahedral environment. The material showed high activity in the oxidative desulfurization of DBT and its activity was not reduced even after three times recycling; further reuse resulted in a gradual decrease in its activity.

• 出版日期2009-8-15
• 单位北京化工大学