Dinuclear based polymeric copper(II) complexes derived from a Schiff base ligand: effect of secondary bridging moieties on geometrical orientations and magnetic properties

作者：Hazra Susanta; Karmakar Anirban; Guedes da Silva M Fatima C; DIhan Lubor; Boca Roman; Pombeiro Armando J L^*

来源：Inorganic Chemistry Communications, 2014, 46: 113-117.

DOI：10.1016/j.inoche.2014.05.025

• Crystal structures
• Coordination polymers
• Phenoxo bridges
• Magnetic properties

[1 + 1] condensation of salicylaldehyde and 2-aminobenzenesulfonic acid led to the formation of the acyclic Schiff base o-[(o-hydroxyphenyl)methylideneamino]benzenesulfonic acid (H2L) which, upon reaction with Cu(II) salts in the presence of triethylamine or 4,4'-bipyridine, formed a 2D polymeric species [Cu2L2](n) (1) via sulfonate bridge and a 1D polymeric complex [{Cu2L2(4,4'-bipy)}center dot DMF](n) (2) via 4,4'-bipyridine bridge, respectively. The copper cations sit on O4N basal- or O3N2 facial-edge-sharing inverted square pyramidal environments in I or 2, respectively. In spite of their comparable compositions, the relative orientations of the metal polyhedra affect the magnetic properties of these polymers since 1, in contrast to 2, presents a strong exchange interaction of an antiferromagnetic nature.

• 出版日期2014-8