A sandwich-type phthalocyaninato metal sextuple-decker complex: synthesis and NLO properties

作者：Wang, Hailong; Qi, Dongdong; Xie, Zheng; Cao, Wei; Wang, Kang; Shang, Hong; Jiang, Jianzhuang^*

来源：Chemical communications, 2013, 49(9): 889-891.

DOI：10.1039/c2cc38088a

• PORPHYRIN ARRAYS
• ABSORPTION
• (NA)PHTHALOCYANINATO
• SPECTROSCOPY
• PHOTOPHYSICS
• ACENES
• TAPES

A hexakis[2,3,9,10,16,17,23,24-octa(butyloxy)phthalocyaninato] samarium(III)-cadmium(II) sextuple-decker complex (Pc*)Sm(Pc*)-Cd(Pc*)Cd(Pc*)Cd(Pc*)Sm(Pc*) (1) with six phthalocyanine ligands bridged by two samarium(III) and three cadmium(II) ions, representing the largest stacked tetrapyrrole metal molecule in the sandwich series in terms of the tetrapyrrole-deck number, has been synthesized and characterized spectroscopically and electrochemically. Investigation of the nonlinear optical properties reveals the excellent optical limiting property of this compound.

• 出版日期2013
• 单位北京科技大学; 中国科学院理化技术研究所