N′-(4-Hydroxybenzylidene)acetohydrazide monohydrate

作者:Lv, Lu-Ping; Yu, Tie-Ming; Yu, Wen-Bo; Li, Wei-Wei; Hu, Xian-Chao*
来源:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65(8): O2007-U4270.
DOI:10.1107/S160053680902892X

摘要

In the title compound, C9H10N2O2 center dot H2O, the molecular skeleton of the acetohydrazide molecule is nearly planar [within 0.014 (1) angstrom]. The molecule adopts a trans configuration with respect to the C=N bond, while the side chain is slightly twisted away from the attached ring, forming a dihedral angle of 9.975 (8)degrees. The crystal packing exhibits a three-dimensional network composed from alternating acetohydrazide molecules and uncoordinated water molecules, which interact via N-H center dot center dot center dot O, O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds. A C-H center dot center dot center dot pi interaction is also present.

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