Aluminum derivative peroxides in the (t-BuO)(3)Al-2t-BuOOH catalytic system as a source of electron-excited dioxygen: a quantum chemical study on a model

作者：Gadzhiev Oleg B; Dodonov Victor A; Petrov Alexander I

来源：RSC Advances, 2016, 6(98): 95542-95555.

DOI：10.1039/c6ra21471a

The t-BuOOH catalytic decomposition leads to reactive oxygen species including chemically activated <graphic xmlns:xlink="http://www.w3.org/1999/xlink" id="ugt1" xlink:href="http://pubs.rsc.org/RA/2016/c6ra21471a/c6ra21471a-t1..gif" /> and chemically excited (O2(b1Σ+g) and O2(1Δg)) dioxygen.

• 出版日期2016