A taylor-made ligand to mimic the active site of diiron enzymes: an air-oxidized high-valent Fe-III h.s.(mu-O)(2)Fe-IV h.s. species

作者:Strautmann Julia B H; Walleck Stephan; Boegge Hartmut; Stammler Anja; Glaser Thorsten*
来源:Chemical Communications, 2011, 47(2): 695-697.
DOI:10.1039/c0cc03098h

摘要

The design and first application of a new dinucleating ligand system to mimic high-valent oxidation states of O-2-dependent diiron enzymes is presented.

  • 出版日期2011