High-rate and long-life of Li-ion batteries using reduced graphene oxide/Co3O4 as anode materials

作者：He Junkai; Liu Ying; Meng Yongtao; Sun Xiangcheng; Biswas Sourav; Shen Min; Luo Zhu; Miao Ran; Zhang Lichun; Mustain William E; Suib Steven L^*

来源：RSC Advances, 2016, 6(29): 24320-24330.

DOI：10.1039/c6ra03790a

Metal oxides as Li-ion battery anodes have received a great deal of attention because they offer a higher specific capacity than state-of-the-art commercial graphite. However, a large volume change and severe particle aggregation during battery operation have greatly impeded their practical application. Herein, we report a facile one-step microwave-assisted route for growing Co3O4 nanoparticles on reduced graphene oxide that results in a high performance anode material for Li-ion batteries. The lithium battery performances of several systems with varied reduced graphene oxide contents were studied. The optimized composites exhibit a high surface area of 222 m(2) g(-1), and a wide pore size distribution of 1.4 to 300 nm. More importantly, the Li-ion battery shows a high capacity of similar to 1300 mA h g(-1) at a high rate of 1C (1C = 890 mA g(-1)), long life of over 600 cycles, good capacity retention, and excellent rate capability. The synthesis process is simple, energy efficient, and time-saving, providing a new path in designing high-performance electrodes for Li-ion batteries.

• 出版日期2016