Aquabis(2,2 ';-bipyridine-kappa N-2,N ';)copper(II) bis(tetrafluoridoborate)

作者：Yu Ming Ming; Zhang Yu Na; Wei Liu He^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M2380-U1227.

DOI：10.1107/S1600536807033557

In the title compound, [Cu(C10H8N2)(2)(H2O)](BF4)(2), the Cu-II atom is coordinated by four N atoms and one O atom in a distorted trigonal-bipyramidal geometry. The Cu-N bond lengths are in the range 1.982 ( 3)-2.124 ( 3) angstrom, while the Cu-O distance is 2.035 ( 4) angstrom. The structure is stabilized by O-H center dot center dot center dot F hydrogen bonds between the Cu-II complex and the tetrafluoridoborate anion. The F atoms of one anion are disordered over two positions; the site occupancy ratio is ca 3: 2.

• 出版日期2007-9
• 单位郑州大学