Modified Synthesis and Supramolecular Polymerization of Rim-to-Rim Connected Bisresorcinarenes

作者:Yamada Hitomi; Ikeda Toshiaki; Mizuta Tsutomu; Haino Takeharu*
来源:Organic Letters, 2012, 14(17): 4510-4513.
DOI:10.1021/ol301996q

摘要

The acid-catalyzed condensation reaction of resorcinol and bisdimethoxyacetals gave rise to rim-to-rim connected bisresorcinarenes in good yields. In the presence of ethanol, the homoditopic bisresorcinarenes assembled to form supramolecular polymers via hydrogen bonding interactions. The fibrous morphologies of the supramolecular polymers were confirmed by atomic force microscopy and scanning electron microscopy.

  • 出版日期2012-9-7