N,N '-Bis[(E)-(3-methyl-2-thienyl)methylidene]ethane-1,2-diamine

作者:Prasath R; Bhavana P; Ng Seik Weng; Tiekink Edward R T*
来源:Acta Crystallographica Section E-Structure Reports Online, 2010, 66: O2884-U796.
DOI:10.1107/S1600536810041632

摘要

Two independent half-molecules, each being completed by inversion symmetry, comprise the asymmetric unit of the title compound, C14H16N2S2. The major difference between the molecules is found in the central C-C bond [the C-N-C-C torsion angles are 114.66 (18) and 128.94 (18)degrees in the two molecules]. The thiophene and imine groups are almost co-planar in each case [S-C-C-N torsion angles = -6.9 (2) and -3.6 (2)degrees]. In the crystal, the molecules aggregate into supramolecular chains via C-H center dot center dot center dot pi interactions.

  • 出版日期2010-11

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