Macrocycle Formation by Proton-Template-Induced Dimerization of Complexes with (Alkoxoimino)pyridine

作者：Alvarez Celedonio M; Garcia Rodriguez Raul; Martin Alvarez Jose M; Miguel Daniel^*; Turiel Jose A

来源：Inorganic Chemistry, 2012, 51(7): 3938-3940.

DOI：10.1021/ic300196w

The existence of a strong hydrogen bond between two molecules of an (alkoxoimino)pyridinemanganese(I) complex induces their dimerization and the formation of a metallamacrocycle. The expected intramolecular attack of the alkoxo moiety is disfavored.

• 出版日期2012-4-2